Hi Donato, welcome to NST.
As you installed W7 to a separate HDD which is now "system", it should have left XP in its original single-boot condition.
You can check by putting the Xp HDD first in the BIOS (with a temporary override using F8 or whatever your BIOS uses to access the boot override dialogue before the power-up splash screen.)
If XP boots normally, you can just make it permanently first in the boot sequence and format the IDE drive.