Welcome to the group.  Whilst the question should really go elsewhere than this Intro thread....
Well according to Google you can import XP/OE6 address book into WLM easy enough....
To import contacts from Outlook Express in Windows Live Mail: 
    Select Go | Contacts from the menu in Windows Live Mail.
        You may have to hold down Alt to see the menu bar. 
    If you want to import Outlook Express contacts from a different computer or old Windows installation:
        Copy the desired .wab file from the computer or installation to the computer running Windows Live Mail.
        Select File | Import | Windows address book (.WAB) from the menu in Windows Live Mail. 
    If you want to import contacts from Outlook Express installed alongside Windows Live Mail:
        Select File | Import | Address book for current Windows user from the menu in Windows Live Mail. 
    Click OK.
Method 2 stolen from Microsoft Forums MVP Bruce Hagen:
Transferring data from Outlook Express to Windows Live Mail: For messages:
 Copy the *ENTIRE* OE message store folder to a flash drive.  (Folders.dbx must be included). Place this on the Desktop or other  location on the machine using WLMail. Open WLMail and: File | Import |  Messages | Microsoft Outlook Express 6 and point to where  you saved it.
 OE Message Store Location:
 In OE: Tools | Options | Maintenance | Store Folder will reveal the  location of your Outlook Express files. Write the location down and  navigate to it in Windows Explorer or, copy and paste it into Start |  Run.
 In WinXP, Win2K & Win2K3, the OE user files (DBX and WAB) are by  default marked as hidden. To view these files in Windows Explorer, you  must enable Show Hidden Files and Folders under Start | Control Panel |  Folder Options Icon | View, or in Windows Explorer  | Tools | Folder Options | View. 
 For Addresses:
 Open the Address Book in OE and File | Export | Address Book (wab)  and save it to the Desktop. Copy to a flash drive. Place this on the  Desktop or other location on the machine using WLMail.
 Open the Contacts list in WLMail, (Go | Contacts on the Menu Bar),  and File | Import | Windows Address Book (wab) and point to where you  saved it. 
 Note: If you use a CD or DVD instead of a flash drive, after placing  on the new machine you must remove the Read Only attribute in Properties  before you import.